Copper(I) oxide



Copper(I) oxide
IUPAC name Copper(I) oxide
Other names Cuprous oxide
Cuprite (mineral)
Red copper oxide
Identifiers
CAS number 1317-39-1
RTECS number GL8050000
Properties
Molecular formula Cu2O
Molar mass 143.09 g/mol
Appearance Brownish-red solid
Density 6.0 g/cm3, solid
Melting point

1235 °C (1508 K)

Solubility in water Insoluble
Structure
Crystal structure cubic
Hazards
MSDS ScienceLab.com
R/S statement R: 22
S: 22
Related Compounds
Other anions Copper(I) sulfide
Copper(II) sulfide
Copper(I) selenide
Other cations Zinc oxide
Except where noted otherwise, data are given for
materials in their standard state
(at 25 °C, 100 kPa)

Infobox disclaimer and references

Copper(I) oxide or cuprous oxide (Cu2O) is an copper(II) nitrate, respectively.

Copper(I) oxide is found as the copper(II) oxide.

Formation of copper(I) oxide is the basis of the precipitate of Cu2O.

Cuprous oxide forms on red plague.

General applications

Cuprous oxide is commonly used as a pigment, a fungicide and an antifouling agent for marine paints.

Applications as semiconductor

Copper(I) oxide was the first substance known to behave as a silicon became the standard.

Copper(I) oxide shows four well understood series of Stark effect and phonoritons have been demonstrated.

Another extraordinary feature of the ground state excitons is that all primary scattering mechanisms are known quantitatively. Cu2O was the first substance where an entirely parameter-free model of polaritons.

See also

References

  1. N. N. Greenwood, A. Earnshaw, Chemistry of the Elements, 2nd ed., Butterworth-Heinemann, Oxford, UK, 1997.
  2. Handbook of Chemistry and Physics, 71st edition, CRC Press, Ann Arbor, Michigan, 1990.
  3. The Merck Index, 7th edition, Merck & Co, Rahway, New Jersey, USA, 1960.
  4. D. Nicholls, Complexes and First-Row Transition Elements, Macmillan Press, London, 1973.
  5. P.W. Baumeister: Optical Absorption of Cuprous Oxide, Phys. Rev. 121 (1961), 359.
  6. L. Brillouin: Wave Propagation and Group Velocity, Academic Press, New York, 1960.
  7. D. Fröhlich, A. Kulik, B. Uebbing, and A. Mysyrovicz: Coherent Propagation and Quantum Beats of Quadrupole Polaritons in Cu2O, Phys. Rev. Lett. 67 (1991), 2343.
  8. L. Hanke: Transformation von Licht in Wärme in Kristallen - Lineare Absorption in Cu2O, ISBN 3-8265-7269-6, Shaker, Aachen, 2000; (Transformation of light into heat in crystals - Linear absorption in Cu2O).
  9. L. Hanke, D. Fröhlich, A.L. Ivanov, P.B. Littlewood, and H. Stolz: LA-Phonoritons in Cu2O, Phys. Rev. Lett. 83 (1999), 4365.
  10. L. Hanke, D. Fröhlich, and H. Stolz: Direct observation of longitudinal acoustic phonon absorption to the 1S-exciton in Cu2O, Sol. Stat. Comm. 112 (1999), 455.
  11. J.J. Hopfield, Theory of the Contribution of Excitons to the Complex Dielectric Constant of Crystals, Phys. Rev. 112 (1958), 1555.
  12. J.P. Wolfe and A. Mysyrowicz: Excitonic Matter, Scientific American 250 (1984), No. 3, 98.
  13. Knovel Critical Tables., Knovel, 2003. http://www.knovel.com/knovel2/Toc.jsp?BookID=761&VerticalID=0
 
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