Hematite



Hematite

General
CategoryOxide mineral
iron(III) oxide, Fe2O3, α-Fe2O3
Identification
ColorMetallic grey to earthy red
Crystal habitTabular to thick crystals
Crystal systemHexagonal (rhombohedral)
CleavageNone
FractureUneven to sub-conchoidal
Mohs Scale hardness5.5 - 6.5
LusterMetallic to splendent
Refractive indexOpaque
PleochroismNone
StreakBright red to dark red
Specific gravity4.9 - 5.3
References[1][2]

Hematite, also spelled hæmatite, is the solid solution at temperatures above 950°C.  

Hematite is a very common mineral, colored black to steel or silver-gray, brown to reddish brown, or red. It is mined as the main ore of iron. Varieties include kidney ore, martite (magnetite), iron rose and specularite (specular hematite). While the forms of hematite vary, they all have a rust-red streak. Hematite is harder than pure iron, but much more brittle.

Huge deposits of hematite are found in volcanic activity.

Clay-sized hematite crystals can also occur as a secondary mineral formed by weathering processes in soil, and along with other iron oxides or oxyhydroxides such as goethite, is responsible for the red color of many tropical, ancient, or otherwise highly weathered soils.

The name hematite is derived from the Greek word for blood (haima) because hematite can be red, as in pigment.  

Good specimens of hematite come from England, Mexico, Brazil, Australia and the Lake Superior region of the United States and Canada.

Magnetism

Hematite is an paramagnetic.  

The magnetic structure of a-hematite was the subject of considerable discussion and debate in the 1950s because it appeared to be ferromagnetic with a Curie temperature of around 1000 K, but with an extremely tiny moment (0.002mB). Adding to the surprise was a transition with a decrease in temperature at around 260 K to a phase with no net magnetic moment.[citation needed]

Dzialoshinksi and later Moriya showed that the system is essentially antiferromagnetic but that the low symmetry of the cation sites allows spin–orbit coupling to cause canting of the moments when they are in the plane perpendicular to the c axis. The disappearance of the moment with a decrease in temperature at 260 K is caused by a change in the anisotropy which causes the moments to align along the c axis. In this configuration, spin canting does not reduce the energy.[citation needed]

Hematite is part of a complex solid solution oxyhydroxide system having various degrees of water, hydroxyl group, and vacancy substitutions that affect the mineral's magnetic and crystal chemical properties.[3] Two other end-members are referred to as protohematite and hydrohematite.

Hematite on Mars

 

The spectral signature of hematite was seen on the planet Mars by the infrared concretions formed from a water solution.

Jewelry

Hematite's popularity in jewelry was at its highest in Europe during the Victorian era, while in the last 50 years it has been popular in North America, especially in the western United States where it is found in jewelry and art created by Native Americans. Care should be taken in handling hematite items due to the material's susceptibility to damage.

See also

 

References

  1. ^ http://webmineral.com/data/Hematite.shtml Webmineral data
  2. ^ http://www.mindat.org/min-1856.html Mindat mineral data
  3. ^ M.-Z. Dang, D.G. Rancourt, J.E. Dutrizac, G. Lamarche, and R. Provencher. Interplay of Surface Conditions, Particle Size, Stoichiometry, Cell Parameters, and Magnetism in Synthetic Hematite-like Materials. Hyperfine Interactions 117 (1998) 271-319.
  4. ^ NASA MGS TES Press Release, May 27 1998 "Mars Global Surveyor TES Instrument Identification of Hematite on Mars", available here
  5. ^ Bandfield, J.L., Global mineral distributions on Mars, J. Geophys Res., 107, 2002. See: Mars Global Data Sets: Hematite Abundance
  6. ^ Glotch, T. D., and P. R. Christensen (2005), "Geologic and mineralogic mapping of Aram Chaos: Evidence for a water-rich history," J. Geophys. Res., 110, E09006, doi:10.1029/2004JE002389 abstract here
  7. ^ T. D. Glotch, D. Rogers, and P. R. Christensen, A Newly Discovered Hematite-Rich Unit in Aureum Chaos: Comparison of Hematite and Associated Units With Those in Aram Chaos, Lunar and Planetary Science Conference XXXVI, 2005
  • Martite - Mindat w/ location data
  • Iron rose - Mindat w/ locations
 
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