Mesoporous silicates




Mesoporous silicates are silicates with a special morphology.

Background

Porous inorganic solids have found great utility as catalysis. The reason for their success is related to their specific features in converting molecules having kinetic diameter below 1 nm, but they become inadequate when reactants with sizes above the dimensions of the pores have to be processed. Research efforts to synthesize zeolites with larger pore diameter, high structural stability and catalytic activity have not given the expected results yet.

Characteristics

The discovery of a new family of mesoporous molecular sieves in the early 1990’s opened new possibilities to prepare catalysts for reactions of relatively large molecules. The most important member of the family, known as MCM-41, possesses regular, hexagonal array of pores with pore diameter in the 1.5-10 nm range. The amorphous. Mesoporous silicates such as MCM-41 and SBA-15 are porous silicates with huge surface areas (normally ≥1000 m²/g), large pore sizes (2 nm ≤ size ≤ 20 nm) and ordered arrays of cylindrical mesopores with very regular pore morphology. The large surface areas of these solids increase the probability that a reactant molecule in solution will come into contact with the catalyst surface and react. The large pore size and ordered pore morphology allow one to be sure that the reactant molecules are small enough to diffuse into the pores.

See also
 
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