Niobium



41 molybdenum
Ta
General
Number niobium, Nb, 41
transition metals
Block d
Appearance gray metallic
(2)  g·mol−1
Kr] 4d4 5s1
shell 2, 8, 18, 12, 1
Physical properties
Phase solid
r.t.) 8.57  g·cm−3
F)
F)
kJ·mol−1
kJ·mol−1
Heat capacity (25 °C) 24.60  J·mol−1·K−1
Vapor pressure
P(Pa) 1 10 100 1 k 10 k 100 k
at T(K) 2942 3207 3524 3910 4393 5013
Atomic properties
Crystal structure cubic body centered
acidic oxide)
Electronegativity 1.6 (Pauling scale)
more) 1st:  652.1  kJ·mol−1
2nd:  1380  kJ·mol−1
3rd:  2416  kJ·mol−1
Atomic radius 145  pm
Atomic radius (calc.) 198  pm
Covalent radius 137  pm
Miscellaneous
Magnetic ordering no data
Electrical resistivity (0 °C) 152 nΩ·m
Thermal conductivity (300 K) 53.7  W·m−1·K−1
Thermal expansion (25 °C) 7.3  µm·m−1·K−1
Speed of sound (thin rod) (20 °C) 3480 m/s
Young's modulus 105  GPa
Shear modulus 38  GPa
Bulk modulus 170  GPa
Poisson ratio 0.40
Mohs hardness 6.0
Vickers hardness 1320  MPa
Brinell hardness 736  MPa
CAS registry number 7440-03-1
Selected isotopes
Main article: Isotopes of niobium
iso NA half-life DM DE (MeV) DP
91Nb syn 6.8×10² y ε - 91Zr
91mNb syn 60.86 d IT 0.104e 91Nb
92Nb syn 10.15 d ε - 92Zr
γ 0.934 -
92Nb syn 3.47×107y ε - 92Zr
γ 0.561, 0.934 -
93Nb 100% Nb is neutrons
93mNb syn 16.13 y IT 0.031e 93Nb
94Nb syn 2.03×104 y β- 0.471 94Mo
γ 0.702, 0.871 -
95Nb syn 34.991 d β- 0.159 95Mo
γ 0.765 -
95mNb syn 3.61 d IT 0.235 95Nb
References

Niobium (alloys as well as in welding, nuclear industries, electronics, optics and jewelry.

Notable characteristics

Niobium is a shiny gray, ductile periodic table.

When it is processed at even moderate temperatures niobium must be placed in a protective atmosphere. The metal begins to oxidation states are +3, and +5, although others are also known.

Niobium has a number of uses: it is a component of some alloy of other nonferrous metals. It is also a very important alloy addition in HSLA steels, which are widely used as structural components in modern automobiles. These alloys are strong and are often used in pipeline construction. Other uses;

  • The metal has a low capture cross-section for thermal neutrons and so finds use in the nuclear industries.
  • It is also the metal used in arc welding rods for some stabilized grades of stainless steel.
  • Appreciable amounts of niobium in the form of high-purity ferroniobium and superalloys for such applications as jet engine components, rocket subassemblies, and heat-resisting and combustion equipment. For example, advanced air frame systems such as those used in the Gemini program used this metal.
  • Niobium is being evaluated as an alternative to tantalum in capacitors.
  • Because niobium and some niobium alloys are physiologically inert (and thus hypoallergenic), they are used in jewelry and in medical devices such as pacemakers. Niobium treated with sodium hydroxide forms a porous layer that aids osseointegration.[4]
  • Along with anodized to a wide array of colors using a process known as reactive metal anodizing. This makes it very attractive for use in jewelry.
  • Niobium is also added to glass in order to attain a higher refractive index, a property used in the optical industry to make thinner corrective glasses.
  • In 2005, the country of Sierra Leone made a coin honoring Pope John Paul II that contained a disc of 24 carat (100%) gold surrounded by a ring of purple-tinted Niobium.

Niobium becomes a superconducting magnets capable of producing exceedingly strong magnetic fields. Niobium is also used in its pure form to make superconducting accelerating structures for particle accelerators.

History

Niobium (Greek mythology: Niobe, daughter of Tantalus) was hydrogen atmosphere.

Columbium (symbol Cb) was the name originally given to this element by Hatchett, but the International Union of Pure and Applied Chemistry (IUPAC) officially adopted "niobium" as the name for element 41 in 1950 after 100 years of controversy. This was a compromise of sorts; the IUPAC accepted tungsten instead of wolfram, in deference to North American usage; and niobium instead of columbium, in deference to European usage. Not everyone agreed, however, and while many leading chemical societies and government organizations refer to it by the official IUPAC name, many leading metallurgists, metal societies, and most leading American commercial producers still refer to the metal by the original "columbium."

Occurrence

  The element is never found as a free element but does occur in the minerals silicate igneous rocks) and as a constituent of pyrochlore. Brazil and Canada are the major producers of niobium mineral concentrates and extensive ore reserves are also in Nigeria, Democratic Republic of Congo, and in Russia. A large producer in Brazil is CBMM located in Araxá, Minas Gerais.

Isotopes

Main article: isotopes of niobium

Naturally occurring niobium is composed of one stable neutron emission occurring in the first mode of the two mode decay of Nb-104, 109 and 110.

Only Nb-95 (35 days) and Nb-97 (72 minutes) and heavier isotopes (halflives in seconds) are used nuclear fuel is slower than would be expected from its own 35 day halflife alone.. Tiny amounts of the other isotopes may be produced as direct fission products.

Precautions

Niobium-containing compounds are relatively rarely encountered by most people, but many are highly toxic and should be treated with care. Metallic niobium dust is an eye and skin irritant and also can be a fire hazard. Niobium has no known biological role.

See also

References

  1. ^ Niobium: niobium(IV) fluoride compound data. WebElements.com. Retrieved on 2007-12-10.
  2. ^ Niobium: niobium(II) oxide compound data. WebElements.com. Retrieved on 2007-12-10.
  3. ^ Niobium: niobium(I) chloride compound data. Bernath.UWaterloo.ca. Retrieved on 2007-12-10.
  4. ^ Godley, Reut; David Starosvetsky, and Irena Gotman (2004). "Bonelike apatite formation on niobium metal treated in aqueous NaOH" (PDF). Journal of Materials Science: Materials in Medicine 15: 1073–1077. doi:10.1023/B:JMSM.0000046388.07961.81. Retrieved on 2006-09-07.
  • Los Alamos National Laboratory – Niobium
 
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