Thioketone



  Thioketones are rings.

Preparative methods

One approach to generating thiocarbonyl-molecules entails treating a Bis(trimethylsilyl)sulfide has also been employed.[1]

Thiobenzophenone, the prototype

  Thiobenzophenone, (C6H5)2CS, is quite stable. This deep benzophenone and sulfur. Since the discovery of thiobenzophenone, a variety of related thiones have been prepared by the Tokitoh group.[2]

Selenones

The Diels-Alder reaction.[3]

See also

Thial, for a description of thioaldehydes.

References

  1. ^ W. M. McGregor, D. C. Sherrington (1993). "Some Recent Synthetic Routes to Thioketones and Thioaldehydes"". Chemical Society Reviews 22: 199 - 204. doi:10.1039/CS9932200199.
  2. ^ a b Okazaki, R.; Tokitoh, N. (2000). "Heavy Ketones, the Heavier Element Congeners of a Ketone". Accounts of Chemical Research 33: 625-630. doi:10.1021/ar980073b.
  3. ^ Erker, G.; Hock, R.; Krüger, C.; Werner, S.; Klärner, F.-G. and Artschwager-Perl, U. (1990). "Synthesis and Cycloadditions of Monomeric Selenobenzophenone". Angewandte Chemie International Edition in English 29: 1067-68. doi:10.1002/anie.199010671.
 
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