Virial expansion



The classical virial expansion expresses the density. The virial expansion was introduced in 1901 by Heike Kamerlingh Onnes as a generalization of the ideal gas law. He wrote for a gas containing N atoms or molecules,

\frac{p}{k_BT} = \rho + B_2(T) \rho^2 +B_3(T) \rho^3+ \cdots,