Potential energy surface



A potential energy surface is generally used within the statistical mechanics to model chemical reactions and interactions in simple chemical and physical systems. The "(hyper)surface" name comes from the fact that the total energy of an atom arrangement can be represented as a curve or (multidimensional) surface, with atomic positions as variables. The best visualization for a layman would be to think of a landscape, where going North-South and East-West are two independent variables (the equivalent of two geometrical parameters of the molecule), and the height of the land we are on would be the energy associated to a given value of such variables.